Para acceder a los documentos con el texto completo, por favor, siga el siguiente enlace: http://hdl.handle.net/2445/99092
Título:
|
Study of the oligomerization of 1-octene catalyzed by macroreticular ion-exchange resins
|
Autor/a:
|
Bringue Tomás, Roger; Cadenas, Madelin; Fité Piquer, Carles; Iborra Urios, Montserrat; Cunill García, Fidel
|
Otros autores:
|
Universitat de Barcelona |
Abstract:
|
Oligomerization of 1-octene is a feasible alternative to improve the properties and the quality of fuels and lubricants oils. The performance of macroreticular ion-exchange resins as catalysts for such reaction has been evaluated. The experimental setup consisted of a batch stirred-tank reactor that operated at 353-393 K and 2 MPa. 1-Octene conversion was practically complete and the selectivity to double-bond isomerization and dimers after 6 h at 373 K was up to 95% and 12%, respectively. The accessible acidity of the catalysts was the most important structural parameter for these reactions. Selectivity to dimers and branched isomers increased with increasing temperature. Cracking compounds were not detected at all. The theoretical equations derived from the proposed kinetic model fit well the experimental results. |
Materia(s):
|
-Resines de bescanvi iònic -Cinètica enzimàtica -Catàlisi -Ion exchange resins -Enzyme kinetics -Catalysis |
Derechos:
|
(c) Elsevier B.V., 2012
|
Tipo de documento:
|
Artículo Artículo - Versión aceptada |
Editor:
|
Elsevier B.V.
|
Compartir:
|
|
Mostrar el registro completo del ítem