Mild ArI-Catalyzed C(sp2)[BOND]H or C(sp3)[BOND]H Functionalization/C[BOND]O Formation: An Intriguing Catalyst-Controlled Selectivity Switch

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Title:	Mild ArI-Catalyzed C(sp2)[BOND]H or C(sp3)[BOND]H Functionalization/C[BOND]O Formation: An Intriguing Catalyst-Controlled Selectivity Switch
Author:	Wang, X.; Gallardo-Donaire, Joan; Martin, Ruben
Abstract:	A tandem C(sp²)H and C(sp³)H functionalization/CO bond formation catalyzed by iodine(III) reagents generated in situ has been developed. The method shows wide scope under mild conditions and exhibits an unprecedented selectivity profile that can be switched depending on the catalyst employed.
Publication date:	2014
Subject(s):	metal-free catalysis site-selectivity C-H functionalization
Rights:	© 1999 - 2016 John Wiley & Sons, Inc.
Document type:	Article
DOI:	https://dx.doi.org/10.1002/anie.201407011
Published by:	Wiley
Publish at:	Angew. Chem. Int.
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