Title:
|
Asymmetric cross- and self-aldol reactions of aldehydes in water with a polystyrene-supported triazolylproline organocatalyst
|
Author:
|
Llanes, Patricia; Sayalero, Sonia; Rodríguez-Escrich, Carles; Pericàs, Miquel A.
|
Abstract:
|
A polystyrene-immobilized triazolylproline has been prepared by a bottom-up approach involving co-polymerization with full regiocontrol. The resulting PS resin swells in water and has been applied to the enantioselective cross-aldol reaction and to the self-aldol reaction of aldehydes under essentially neat conditions, excellent yields and stereoselectivities being recorded. |
Publication date:
|
2016 |
Rights:
|
© Royal Society of Chemistry 2016 |
Document type:
|
Article |
DOI:
|
https://dx.doi.org/10.1039/C6GC00792A
|
Published by:
|
Royal Society of Chemistry
|
Publish at:
|
Green Chemistry
|
Share:
|
|