In energy-harvesting applications, inductor-based switching dc/dc converters are usually employed to regulate the operating voltage of the energy transducer and to transfer the harvested energy to a storage unit. In such a context, this paper analyses the optimal inductor current of the converter that leads to maximum power efficiency. This is evaluated assuming a low-power photovoltaic (PV) module connected to a boost dc/dc converter operating in burst mode so as to reduce the switching losses. The theoretical analysis and the experimental results reported herein prove that this optimal inductor current does not depend on the power generated by the PV module provided that the control circuit is powered from the output, but it does on the output voltage level of the storage unit. Experimental tests with a commercial boost dc/dc converter show that the use of this optimal inductor current provides up to 10% increase in efficiency.