Gold(I)-Catalyzed Inter- and Intramolecular Additions of Carbonyl Compounds to Allenenes

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Title:	Gold(I)-Catalyzed Inter- and Intramolecular Additions of Carbonyl Compounds to Allenenes
Author:	Jiménez, Tania; Carreras, Javier; Ceccon, Julien; Echavarren, Antonio M.
Abstract:	The gold(I)-catalyzed intramolecular reaction of allenes with oxoalkenes leads to bicyclo[6.3.0]undecane ring systems, although in the case of terminally disubstituted allenes, seven-membered rings are formed. The related intermolecular addition of aldehydes to allenenes also gives seven-membered rings.
Publication date:	2016-02-26
Subject(s):	Quimica Quimica
Rights:	L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/
Pages:	1410 p.
Document type:	Article Article - Draft
DOI:	10.1021/acs.orglett.6b00342
Published by:	Org. Lett.
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