Alkyl Bromides as Mild Hydride Sources in Ni-Catalyzed Hydroamidation of Alkynes with Isocyanates

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Use this identifier to quote or link this document: http://hdl.handle.net/2072/326406

Title:	Alkyl Bromides as Mild Hydride Sources in Ni-Catalyzed Hydroamidation of Alkynes with Isocyanates
Author:	Wang, Xueqiang; Nakajima, Masaki; Serrano, Eloisa; Martin, Ruben
Abstract:	A catalytic hydroamidation of alkynes with isocyanates using alkyl bromides as hydride sources has been developed. The method turns parasitic β-hydride elimination into a strategic advantage, rapidly affording acrylamides with excellent chemo- and regioselectivity.
Publication date:	2016-11-17
Subject(s):	Quimica
Rights:	L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/
Pages:	15531 p.
Document type:	Article Article - Draft
DOI:	10.1021/jacs.6b10351
Published by:	J. Am. Chem. Soc
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