Títol:
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Catalytic Asymmetric Diamination of Styrenes
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Autor/a:
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Muñiz, Kilian; Barreiro, Laura; Romero, Martín; Martínez, Claudio
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Abstract:
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An enantioselective catalytic vicinal diamination of styrenes is reported, which proceeds under entirely intermolecular reaction control. It relies on a chirally modified aryliodine(I) catalyst and proceeds within an iodine(I/III) manifold with conventional 3-chloroperbenzoic acid as a terminal oxidant. An environmentally benign solvent combination not only adds to the attractiveness of the process but also slows down the rate of the undesired background reaction. A total of 30 examples are presented, which consistently provide high enantiomeric excesses in the range 91–98%. |
Data de publicació:
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09-03-2017 |
Matèries:
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Quimica |
Drets:
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L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/ |
Pàgines:
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4354 p. |
Tipus de document:
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Article Article - Esborrany |
Publicat per:
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J. Am. Chem. Soc.
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