dc.contributor.author |
Puy Llorens, Jaume |
dc.contributor.author |
Cecilia Averós, Joan |
dc.contributor.author |
Galceran i Nogués, Josep |
dc.contributor.author |
Town, Raewyn M. |
dc.contributor.author |
Leeuwen, Herman P. van |
dc.date |
2015-11-10T10:41:39Z |
dc.date |
2015-11-10T10:41:39Z |
dc.date |
2004 |
dc.date |
2015-11-10T10:41:39Z |
dc.identifier |
1572-6657 |
dc.identifier |
http://hdl.handle.net/10459.1/48940 |
dc.identifier |
https://doi.org/10.1016/j.jelechem.2004.04.017 |
dc.identifier.uri |
http://hdl.handle.net/10459.1/48940 |
dc.description |
The voltammetric lability of a complex system, where a metal ion M and a ligand L form the species ML and ML2, is examined. Together with the rigorous numerical simulation of the problem, two limiting cases are analysed for the overall process ML2 → M: (i) the most common case for aqueous complexes, where ML → M is the kinetically limiting step and (ii) the case where ML2 → ML is limiting. In both cases, analytical expressions for the lability criteria are provided which show good agreement with the results obtained from the rigorous numerical simulation of the problem. |
dc.format |
application/pdf |
dc.language |
eng |
dc.publisher |
Elsevier |
dc.relation |
Versió postprint del document publicat a: https://doi.org/10.1016/j.jelechem.2004.04.017 |
dc.relation |
Journal of Electroanalytical Chemistry, 2004, vol. 571, num. 2, p. 121-132 |
dc.rights |
(c) Elsevier, 2004 |
dc.rights |
info:eu-repo/semantics/openAccess |
dc.subject |
Voltametria |
dc.subject |
Metalls |
dc.subject |
Voltammetry |
dc.subject |
Metals |
dc.title |
Voltammetric lability of multiligand complexes: the case of ML2 |
dc.type |
info:eu-repo/semantics/article |
dc.type |
info:eu-repo/semantics/acceptedVersion |