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| Title: | Stereospecific SN2@P reactions: Novel access to bulky P-stereogenic ligands |
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| Author: | Orgué Gassol, Sílvia; Flores-Gaspar, Areli; Biosca, Maria; Pàmies, Oscar; Diéguez, Montserrat; Riera i Escalé, Antoni; Verdaguer i Espaulella, Xavier |
| Other authors: | Universitat de Barcelona |
| Abstract: | The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands. |
| Subject(s): | -Hidròlisi -Lligands -Catàlisi asimètrica -Compostos de bor -Hydrolysis -Ligands -Enantioselective catalysis -Boron compounds |
| Rights: | cc by (c) Orgué Gassol, Sílvia et al., 2015
http://creativecommons.org/licenses/by/3.0/es/ |
| Document type: | Article Article - Published version |
| Published by: | Royal Society of Chemistry |
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