Title:
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Preparation and Double Michael Addition Reactions of a Synthetic Equivalent of Nazarov Reagent
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Author:
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Amat Tusón, Mercedes; Arioli, Federica; Pérez Bosch, Maria; Molins i Grau, Elies; Bosch Cartes, Joan
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Other authors:
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Universitat de Barcelona |
Abstract:
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A synthetic equivalent of the Nazarov reagent, the silyl derivative 2, able to undergo base-catalyzed double Michael addition reactions with a,b-unsaturated carbonyl compounds, has been developed. The new reagent satisfactorily reacts with unsaturated indolo[2,3-a]quinolizidine lactams to give pentacyclic yohimbinone-type derivatives. |
Subject(s):
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-Indicadors (Química) -Proves i reactius químics -Lactames -Indicators and test-papers -Chemical tests and reagents -Lactams |
Rights:
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(c) American Chemical Society , 2013
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Document type:
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Article Article - Accepted version |
Published by:
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American Chemical Society
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