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Glassy Anomalies in the Low-Temperature Thermal Properties of a Minimally Disordered Crystalline Solid
Gebbia, Jonathan Fernando; Ramos, M. A.; Szewczyk, Daria; Jezowski, Andrzej; Krivchikov, Alexander; Horbatenko, Y.V; Guidi, T.; Bermejo, F. J.; Tamarit Mur, José Luis
Universitat Politècnica de Catalunya. Departament de Física; Universitat Politècnica de Catalunya. GCM - Grup de Caracterització de Materials
The low-temperature thermal and transport properties of an unusual kind of crystal exhibiting minimal molecular positional and tilting disorder have been measured. The material, namely, low-dimensional, highly anisotropic pentachloronitrobenzene has a layered structure of rhombohedral parallel planes in which the molecules execute large-amplitude in-plane as well as concurrent out-of-plane librational motions. Our study reveals that low-temperature glassy anomalies can be found in a system with minimal disorder due to the freezing of (mostly in-plane) reorientational jumps of molecules between equivalent crystallographic positions with partial site occupation. Our findings will pave the way to a deeper understanding of the origin of the above-mentioned universal glassy properties at low temperature.
Peer Reviewed
-Àrees temàtiques de la UPC::Física
-Anisotropy
-Crystals
-Anisotropia
-Cristalls
Attribution-NonCommercial-NoDerivs 3.0 Spain
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
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