dc.contributor.author |
Bansode, Atul |
dc.contributor.author |
Urakawa, Atsushi |
dc.date.accessioned |
2018-01-15T16:03:47Z |
dc.date.accessioned |
2018-02-15T10:28:47Z |
dc.date.available |
2018-01-15T16:03:47Z |
dc.date.available |
2018-02-15T10:28:47Z |
dc.date.issued |
2014 |
dc.identifier.uri |
http://hdl.handle.net/2072/226257 |
dc.identifier.uri |
http://hdl.handle.net/2072/305896 |
dc.language.iso |
eng |
dc.publisher |
ACS Publications |
dc.relation |
ICIQ Foundation |
dc.relation |
MINECO |
dc.relation |
Severo Ochoa Excellence Accreditation 2014-2018 |
dc.relation.ispartof |
ACS Catalysis |
dc.rights |
© 2014 American Chemical Society |
dc.subject.other |
heterogeneous catalysis |
dc.subject.other |
CO2 conversion |
dc.subject.other |
dimethyl carbonate |
dc.subject.other |
dehydrating agent |
dc.subject.other |
2-cyanopyridine |
dc.subject.other |
high pressure |
dc.subject.other |
methanol |
dc.subject.other |
conversion |
dc.subject.other |
continuous flow |
dc.subject.other |
fixed bed reactor |
dc.title |
Continuous DMC synthesis from CO2 and methanol over CeO2 catalyst in fixed bed reactor in presence of dehydrating agent |
dc.type |
info:eu-repo/semantics/article |
dc.relation.projectID |
SEV-2013-0319 |
dc.relation.projectID |
CTQ2012-34153 |
dc.identifier.doi |
https://dx.doi.org/10.1021/cs501221q |
dc.rights.accessLevel |
info:eu-repo/semantics/openAccess |
dc.description.abstract |
Methanol and carbon dioxide are continuously and efficiently converted to dimethyl carbonate (DMC) over CeO2 catalyst using 2-cyanopyrindine as a recyclable dehydrating agent in a fixed bed reactor. The process was operated over a wide range of pressure (1-300 bar) by feeding CO2 and the stoichiometric amount of methanol and 2-cyanopyrinde mixture into the reactor. The study shows successful demonstration of direct DMC synthesis mediated by dehydrating agent with outstanding methanol conversion (>95%) and dimethyl carbonate selectivity (>99%) under optimized conditions. Remarkably higher reaction rates were achieved compared to those in batch operation. |