dc.contributor.author |
Martín, Carmen |
dc.contributor.author |
Whiteoak, Cristopher J. |
dc.contributor.author |
Martin, Eddy |
dc.contributor.author |
Escudero-Adán, Eduardo C. |
dc.contributor.author |
Galán-Mascarós, José-Ramón |
dc.contributor.author |
Klei, Arjan W. |
dc.date.accessioned |
2018-01-15T16:04:02Z |
dc.date.accessioned |
2018-02-15T10:29:01Z |
dc.date.available |
2018-01-15T16:04:02Z |
dc.date.available |
2018-02-15T10:29:01Z |
dc.date.issued |
2014 |
dc.identifier.uri |
http://hdl.handle.net/2072/226292 |
dc.identifier.uri |
http://hdl.handle.net/2072/305935 |
dc.language.iso |
eng |
dc.publisher |
ACS |
dc.relation |
Icrea |
dc.relation |
MINECO |
dc.relation |
Severo Ochoa |
dc.relation |
ERC Stg Grant CHEMCOMP |
dc.relation |
Marie Curie,Cofund |
dc.relation |
Icrea,MINECO,Severo Ochoa,ERC Stg Grant CHEMCOMP,Marie Curie,Cofund |
dc.relation.ispartof |
Inorg. Chem |
dc.rights |
© 2014 American Chemical Society |
dc.title |
Synthesis and Structural Features of Co(II) and Co(III) Complexes Supported by Aminotrisphenolate Ligand Scaffolds |
dc.type |
info:eu-repo/semantics/article |
dc.relation.projectID |
CTQ-2011- 27385 |
dc.relation.projectID |
Severo Ochoa Excellence Accreditation 2014-2018 (SEV-2013-0319) |
dc.identifier.doi |
https://dx.doi.org/10.1021/ic501883z |
dc.rights.accessLevel |
info:eu-repo/semantics/openAccess |
dc.description.abstract |
Co(II) complexes of aminotrisphenolate ((ArO)3N3−) ligands can be prepared straightforwardly in high yield. X-ray analysis reveals these complexes to comprise of two different hemispheres, one containing an anionic Co((ArO)3N)− and the other a cationic (ArO)3NH+ unit, which are associated through hydrogen bonding. These Co(II) complexes can be easily converted into their Co(III) analogues in air in the presence of suitable bases such as dimethylaminopyridine and 2,2′-bipyridine, and the structural features and magnetic properties of these latter compounds are also reported. |