Thermal decomposition of barium trifluoroacetate thin films

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dc.contributor	Ministerio de Ciencia e Innovación (Espanya)
dc.contributor	Generalitat de Catalunya. Agència de Gestió d'Ajuts Universitaris i de Recerca
dc.contributor.author	Eloussifi, Hichem
dc.contributor.author	Farjas Silva, Jordi
dc.contributor.author	Roura Grabulosa, Pere
dc.contributor.author	Ricart, Susagna
dc.contributor.author	Puig, Teresa
dc.contributor.author	Obradors, Xavier
dc.contributor.author	Dammak, Mohamed Chedly
dc.date	2015-01-13T09:20:51Z
dc.date	2017-01-13T04:00:05Z
dc.date	2013
dc.identifier.citation	0040-6031
dc.identifier.citation	017611
dc.identifier.uri	http://hdl.handle.net/10256/9833
dc.format	application/pdf
dc.language.iso	eng
dc.publisher	Elsevier
dc.relation	http://dx.doi.org/10.1016/j.tca.2013.01.022
dc.relation	MICINN/PN 2012-2014/MAT2011-28874-C02-02
dc.relation	AGAUR/2009-2013/2009 SGR-185
dc.relation	Versió postprint del document publicat a: http://dx.doi.org/10.1016/j.tca.2013.01.022
dc.relation	© Thermochimica Acta, 2013, vol. 556, p. 58-62
dc.relation	Articles publicats (D-F)
dc.rights	Tots els drets reservats
dc.rights	info:eu-repo/semantics/openAccess
dc.subject	Mass spectrometry
dc.subject	Thin films
dc.subject	Espectrometria de masses
dc.subject	Compostos de bari
dc.subject	Barium compounds
dc.subject	Capes fines
dc.subject	Anàlisi tèrmica
dc.subject	Thermal analysis
dc.subject	Capes fines de compostos de bari
dc.subject	Thin films barium compounds
dc.title	Thermal decomposition of barium trifluoroacetate thin films
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/acceptedVersion
dc.description.abstract	The thermal decomposition of barium trifluoroacetate thin films under different atmospheres is presented. Thermogravimetry and evolved gas analysis have been used for this in situ analysis. We focus our attention on the different behavior exhibited by films when compared to powders. The decomposition of barium trifluoroacetate is altered due to the faster out-diffusion of the product reaction:CF2. After barium trifluoroacetate decomposition a stable intermediate, barium fluoride, is formed. The decomposition of barium fluoride is diffusion controlled and depends on water partial pressure
dc.description.abstract	This work was partially funded by the Spanish Programa Nacional de Materiales through projects MAT2011-28874-C02-01 and MAT2011-28874-C02-02, by the Consolider program Nanoselect, CSD2007-00041, EU project NESPA-RTN and by the Generalitat de Catalunya contracts No. 2009SGR-185 and 2009SGR-770

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