dc.contributor.author |
Ranieri, Beatrice |
dc.contributor.author |
Obradors, Carla |
dc.contributor.author |
Mato, Mauro |
dc.contributor.author |
Echavarren, Antonio M. |
dc.date.accessioned |
2018-06-15T12:03:25Z |
dc.date.available |
2018-06-15T12:03:25Z |
dc.date.issued |
2016-05-14 |
dc.identifier.uri |
http://hdl.handle.net/2072/326401 |
dc.format.extent |
1614 p. |
dc.language.iso |
cat |
dc.rights |
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/ |
dc.source |
RECERCAT (Dipòsit de la Recerca de Catalunya) |
dc.subject.other |
Quimica |
dc.title |
Synthesis of Rumphellaone A and Hushinone by a Gold-Catalyzed [2 + 2] Cycloaddition |
dc.type |
info:eu-repo/semantics/article |
dc.type |
info:eu-repo/semantics/draft |
dc.embargo.terms |
cap |
dc.relation.projectID |
321066 |
dc.identifier.doi |
10.1021/acs.orglett.6b00473 |
dc.rights.accessLevel |
info:eu-repo/semantics/openAccess |
dc.description.abstract |
The enantioselective total synthesis of rumphellaone A has been accomplished in 12 steps via a diastereoselective gold(I)-catalyzed [2 + 2] macrocyclization of a 1,10-enyne as the key step to build the cyclobutene moiety. This concise approach has also led to the total synthesis of husinone. |