Title:
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Visible Light-Promoted Atom Transfer Radical Cyclization of Unactivated Alkyl Iodides
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Author:
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Shen, Yangyang; Cornella, Josep; Juliá-Hernández, Francisco; Martin; Martin, Ruben
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Abstract:
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A visible-light-mediated atom transfer radical cyclization of unactivated alkyl iodides is described. This protocol operates under mild conditions and exhibits high chemoselectivity profile while avoiding parasitic hydrogen atom transfer pathways. Preliminary mechanistic studies challenge the perception that a canonical photoredox catalytic cycle is being operative. |
Publication date:
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2016-12-06 |
Subject(s):
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Quimica |
Rights:
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L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/ |
Pages:
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409 p. |
Document type:
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Article Article - Draft |
DOI:
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10.1021%2Facscatal.6b03205%20
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Published by:
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ACS Catal.
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