Dual Intermolecular Allylic C-H Functionalization within the Tetrasubstituted Alkene Scaffold

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dc.contributor.author	Martínez, Claudio
dc.contributor.author	Muñiz, Kilian
dc.date.accessioned	2018-06-15T14:18:39Z
dc.date.available	2019-01-18T01:45:05Z
dc.date.issued	2018-01-18
dc.identifier.uri	http://hdl.handle.net/2072/326413
dc.format.extent	1248 p.
dc.language.iso	eng
dc.publisher	Eur. J. Org. Chem.
dc.rights	L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source	RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other	Quimica
dc.title	Dual Intermolecular Allylic C-H Functionalization within the Tetrasubstituted Alkene Scaffold
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/draft
dc.embargo.terms	12 mesos
dc.identifier.doi	10.1002/ejoc.201701624
dc.rights.accessLevel	info:eu-repo/semantics/openAccess
dc.description.abstract	Activation of chloramine‐T (TsNNaCl) with a Brønsted acid generates an active reagent for the double allylic C–H functionalization of tetrasubstituted alkenes in an intermolecular manner. The reaction generates a carbon–nitrogen and a carbon–chlorine bond, and proceeds with complete regio‐ and chemoselectivity. A total of 14 examples demonstrate the applicability of the dual C–H functionalization process. The mechanism involves the intermediacy of a 1,3‐butadiene derivative; 1,3‐butadienes can also be used directly as substrates.

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