From isodesmic to highly cooperative: Reverting the supramolecular polymerization mechanism in water by fine monomer design

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dc.contributor.author	Casellas, Nicolas M.
dc.contributor.author	Pujals Riatós, Silvia
dc.contributor.author	Bochicchio, Davide
dc.contributor.author	Pavan, Giovanni M.
dc.contributor.author	Torres, Tomás
dc.contributor.author	Albertazzi, Lorenzo
dc.contributor.author	García Iglesias, Miguel
dc.date	2019-01-17T14:10:41Z
dc.date	2019-03-27T06:10:36Z
dc.date	2018-03-27
dc.identifier.uri	http://hdl.handle.net/2445/127393
dc.format	4 p.
dc.format	application/pdf
dc.language.iso	eng
dc.relation	Versió postprint del document publicat a: http://dx.doi.org/10.1039/C8CC01259H
dc.relation	Chemical Communications, 2018, vol. 54, num. 33, p. 4112-4115
dc.relation	https://doi.org/10.1039/C8CC01259H
dc.rights	(c) Casellas et al., 2018
dc.rights	info:eu-repo/semantics/openAccess
dc.subject	Polimerització
dc.subject	Estructura molecular
dc.subject	Aigua
dc.subject	Polymerization
dc.subject	Molecular structure
dc.subject	Water
dc.title	From isodesmic to highly cooperative: Reverting the supramolecular polymerization mechanism in water by fine monomer design
dc.type	info:eu-repo/semantics/article
dc.description.abstract	Two structurally-similar discotic molecules able to self-assemble in water, forming supramolecular fibers, are reported. While both self-assembled polymers are indistinguishable from a morphological point-of-view, a dramatic change in their polymerization mechanism is observed (i.e., one self-assemble via an isodesmic mechanism, while the other shows one of the highest cooperativity values).