General and stereoselective aminoxylation of biradical titanium(IV) enolates with TEMPO: a detailed study on the effect of the chiral auxiliary

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Title:	General and stereoselective aminoxylation of biradical titanium(IV) enolates with TEMPO: a detailed study on the effect of the chiral auxiliary
Author:	Kennington, Stuart C. D.; Gómez Palomino, Alejandro; Salomo, Ernest; Romea, Pedro; Urpí Tubella, Fèlix; Font Bardia, Ma. Mercedes
Other authors:	Universitat de Barcelona
Abstract:	A comprehensive analysis of the influence of the chiral auxiliary on the α-aminoxylation of titanium(IV) enolates with TEMPO indicated that (S) 4-tert-butyl-1-oxazolidine-2-thione is the most appropriate scaffold to provide a single diastereomer in high yields for a variety of substrates, which converts such a radical reaction into a highly chemo- and stereoselective oxidation
Subject(s):	-Titani -Estereoquímica -Titanium -Stereochemistry
Rights:	(c) Kennington, Stuart C. D. et al., 2018
Document type:	Article Article - Accepted version
Published by:	Royal Society of Chemistry
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