Title:
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Cyclopropane-Alkene Metathesis by Gold(I)-Catalyzed Decarbenation of Persistent Cyclopropanes
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Author:
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Mato, Mauro; Martín-Torres, Inmaculada; Herlé, Bart; Echavarren, Antonio M.
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Abstract:
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A gold(I)-catalyzed cyclopropane-alkene metathesis has been demonstrated with two new families of cyclopropane derivatives of naphthalene and phenanthrene (benzo-fused norcaradienes). In this process, metal carbene units are transferred from a persistent cyclopropane to an alkene, upon release of naphthalene or phenanthrene, allowing the diastereoselective synthesis of a wide range of aryl and vinyl cyclopropanes. |
Publication date:
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2019-03-27 |
Subject(s):
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54 |
Rights:
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L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/ |
Pages:
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4216 p. |
Document type:
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Article Article - Accepted version |
DOI:
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10.1039/C9OB00359B
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