Generation of Gold(I) Carbenes by Retro-Buchner Reaction: From Cyclopropanes to Natural Products Synthesis

doi:10.1002/cctc.201801201

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RECERCAT Home > Centres de Recerca de Catalunya (CERCA) > Institut Català d'Investigació Química (ICIQ) > Papers > View document

Use this identifier to quote or link this document: http://hdl.handle.net/2072/368031

dc.contributor.author	Mato, Mauro
dc.contributor.author	García-Morales, Cristina
dc.contributor.author	Echavarren, Antonio M.
dc.date.accessioned	2020-01-17T15:28:22Z
dc.date.available	2020-01-17T15:28:22Z
dc.date.issued	2018-09-01
dc.identifier.uri	http://hdl.handle.net/2072/368031
dc.format.extent	53 p.
dc.language.iso	eng
dc.rights	L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source	RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other	54
dc.title	Generation of Gold(I) Carbenes by Retro-Buchner Reaction: From Cyclopropanes to Natural Products Synthesis
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/acceptedVersion
dc.embargo.terms	cap
dc.relation.projectID	CTQ2016-75960-P
dc.relation.projectID	SEV-2013-0319
dc.relation.projectID	Advanced Grant No. 321066
dc.relation.projectID	AGAUR (2017 SGR 1257)
dc.identifier.doi	10.1002/cctc.201801201
dc.rights.accessLevel	info:eu-repo/semantics/openAccess
dc.description.abstract	The gold(I)-catalyzed retro-Buchner (decarbenation, retrocyclopropanation) reaction of 7-substituted cycloheptatrienes has emerged as a safe and powerful alternative for the generation of gold(I) carbenes. These carbenes can cyclopropanate alkenes, take part in intramolecular reactions, or engage in higher cycloadditions with different partners, giving rise to a wide range of relevant structures. This review covers the developments made on the generation of gold(I) carbenes via decarbenation reactions, and the applications of these reactions in organic synthesis.

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