Título: | Confining Functional Nanoparticles into Colloidal Imine-Based COF Spheres by a Sequential Encapsulation-Crystallization Method |
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Autor/a: | Rodríguez-San-Miguel, David; Yazdi, Amirali; Guillerm, Vincent; Pérez-Carvajal, Javier; Puntes, Víctor; Maspoch Comamala, Daniel; Zamora, Félix |
Abstract: | Altres ajuts: Generalitat de Catalunya for a Beatriu de Pinós fellowship (2014 BP-B 00155) |
Abstract: | Here, a two-step method is reported that enables imparting new functionalities to covalent organic frameworks (COFs) by nanoparticle confinement. The direct reaction between 1,3,5-tris(4-aminophenyl)benzene and 1,3,5-benzenetricarbaldehyde in the presence of a variety of metallic/metal-oxide nanoparticles resulted in embedding of the nanoparticles in amorphous and non-porous imine-linked polymer organic spheres (NP@a-1). Post-treatment reactions of NP@a-1 with acetic acid under reflux led to crystalline and porous imine-based COF-hybrid spheres (NP@c-1). Interestingly, Au@c-1 and Pd@c-1 were found to be catalytically active. |
Materia(s): | -Covalent organic frameworks -Crystallization -Encapsulation -Hybrids -Nanoparticles |
Derechos: | open access
Tots els drets reservats. https://rightsstatements.org/vocab/InC/1.0/ |
Tipo de documento: | Article |
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Uri: | https://ddd.uab.cat/record/210802 |