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Empreu aquest identificador per citar o enllaçar aquest document: http://hdl.handle.net/2072/535777
| dc.contributor.author | Sarkar, Sayan |
|---|---|
| dc.contributor.author | Ballester, Pablo |
| dc.contributor.author | Spektor, Mark |
| dc.contributor.author | Kataev, Evgeny A. |
| dc.date.accessioned | 2023-06-29T13:59:31Z |
| dc.date.available | 2023-06-29T13:59:31Z |
| dc.date.issued | 2022-11-23 |
| dc.identifier.uri | http://hdl.handle.net/2072/535777 |
| dc.description.abstract | The design of high-affinity synthetic host–guest complexes is of paramount importance because they are key elements in constructing unprecedented supramolecular assemblies, functional materials, molecular probes, artificial signal transduction events, and interfaces with the biological world. The present review article collects recent achievements in the design of 1 : 1 host–guest complexes with outstanding stabilities, i.e., exceeding 106 M−1. The relationships between the measured thermodynamic constants and the structural parameters of the interacting species are analyzed. The design features of high-affinity hosts are discussed in light of their binding properties. Different solvents and different types of noncovalent interactions are considered for the stabilization of the complexes. Finally, some hints are provided for the design of future synthetic receptors displaying high affinity and selectivity. |
| dc.format.extent | 26 p. |
| dc.language.iso | eng |
| dc.publisher | Wiley-VCH |
| dc.rights | Creative Commons. Attribution 4.0 International (CC BY 4.0) |
| dc.source | RECERCAT (Dipòsit de la Recerca de Catalunya) |
| dc.subject.other | Química |
| dc.title | Micromolar Affinity and Higher: Synthetic Host–Guest Complexes with High Stabilities |
| dc.type | info:eu-repo/semantics/article |
| dc.type | info:eu-repo/semantics/publishedVersion |
| dc.subject.udc | 00 - Ciència i coneixement. Investigació. Cultura. Humanitats |
| dc.embargo.terms | cap |
| dc.relation.projectID | Deutsche Forschungsgemeinschaft, projects KA 3444/16-1 and SFB 953 |
| dc.relation.projectID | Gobierno de España MICINN/AEI/FEDER (PID2020-114020GB-I00 and CEX2019-000925-S) |
| dc.relation.projectID | European Union (NOAH project H2020-MSCA-ITN project Ref. 765297) |
| dc.relation.projectID | CERCA Programme/Generalitat de Catalunya |
| dc.relation.projectID | AGAUR (2017 SGR 1123) |
| dc.relation.projectID | Open Access funding enabled and organized by Projekt DEAL |
| dc.identifier.doi | 10.1002/anie.202214705 |
| dc.rights.accessLevel | info:eu-repo/semantics/openAccess |
Text complet d'aquest document
| Fitxers | Mida | Format |
|---|---|---|
| Angew Chem Int ... with High Stabilities.pdf | 20.44 MB |
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