Modification of epoxy-anhydride thermosets using a hyperbranched poly(este-amide): I. Kinetic study

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To access the full text documents, please follow this link: http://hdl.handle.net/2117/18689

dc.contributor	Universitat Politècnica de Catalunya. Departament de Màquines i Motors Tèrmics
dc.contributor	Universitat Politècnica de Catalunya. TERFIQ - Grup de Termodinàmica i Fisico-Química
dc.contributor.author	Fernández Francos, Xavier
dc.contributor.author	Rybak, Andrzej
dc.contributor.author	Sekula, Robert
dc.contributor.author	Ramis Juan, Xavier
dc.contributor.author	Serra, Angels
dc.date	2012-05-16
dc.identifier.citation	Fernández-Francos, X. [et al.]. Modification of epoxy-anhydride thermosets using a hyperbranched poly(este-amide): I. Kinetic study. "Polymer international", 16 Maig 2012, vol. 61, núm. 12, p. 1710-1725.
dc.identifier.citation	0959-8103
dc.identifier.citation	10.1002/pi.4259
dc.identifier.uri	http://hdl.handle.net/2117/18689
dc.language.iso	eng
dc.rights	Attribution-NonCommercial-NoDerivs 3.0 Spain
dc.rights	info:eu-repo/semantics/openAccess
dc.rights	http://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.subject	Àrees temàtiques de la UPC::Enginyeria química::Química física::Cinètica
dc.subject	Àrees temàtiques de la UPC::Enginyeria dels materials::Materials plàstics i polímers
dc.subject	Chemical kinetics
dc.subject	Epoxy resins
dc.subject	Cinètica química
dc.subject	Polímers
dc.title	Modification of epoxy-anhydride thermosets using a hyperbranched poly(este-amide): I. Kinetic study
dc.type	info:eu-repo/semantics/publishedVersion
dc.type	info:eu-repo/semantics/article
dc.description.abstract	An epoxy-anhydride formulation used for the coating of electrical devices was modified with a commercially available hyperbranched poly(ester-amide), HybraneS2200, in order to improve the thermal degradability of the resulting thermoset and thus facilitate the recovery of substrate materials after use of the component. The curing kinetics of the unmodified and modifiedformulationswerestudied in detail with differential scanning calorimetry,Fourier transform infrared spectroscopyand rheology. The results suggest that S2200 gets incorporated into the network structure and the curing kinetics are accelerated by the presence of hydroxyl groups from S2200.

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