Selective Ortho-Hydroxylation–Defluorination of 2-Fluorophenolates with a Bis(m-oxo)dicopper(III) Species

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dc.contributor.author	Serrano Plana, Joan
dc.contributor.author	Garcia Bosch, Isaac
dc.contributor.author	Miyake, Ryosuke
dc.contributor.author	Costas Salgueiro, Miquel
dc.contributor.author	Company Casadevall, Anna
dc.date	2014
dc.identifier.citation	1433-7851 (versió paper)
dc.identifier.citation	1521-3773 (versió electrònica)
dc.identifier.citation	http://dx.doi.org/10.1002/ange.201405060
dc.identifier.uri	http://hdl.handle.net/10256/10332
dc.format	application/pdf
dc.language.iso	eng
dc.publisher	Wiley-VCH Verlag
dc.relation	Reproducció digital del document publicat a: http://dx.doi.org/10.1002/ange.201405060
dc.relation	© Angewandte Chemie-International Edition, 2014, vol. 53, p. 9608 –9612
dc.relation	Articles publicats (D-Q)
dc.relation	info:eu-repo/grantAgreement/EC/FP7/303522
dc.rights	Tots els drets reservats
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	Coure -- Compostos
dc.subject	Copper compounds
dc.title	Selective Ortho-Hydroxylation–Defluorination of 2-Fluorophenolates with a Bis(m-oxo)dicopper(III) Species
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/publishedVersion
dc.description.abstract	The bis(mu-oxo) dicopper(III) species [Cu-III 2(mu-O)(2)(m-XYLMeAN)](2+) (1) promotes the electrophilic ortho-hydroxylation-defluorination of 2-fluorophenolates to give the corresponding catechols, a reaction that is not accomplishable with a (eta(2) : eta(2)-O-2) dicopper(II) complex. Isotopic labeling studies show that the incoming oxygen atom originates from the bis(mu-oxo) unit. Ortho-hydroxylation-defluorination occurs selectively in intramolecular competition with other ortho-substituents such as chlorine or bromine

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