Title:
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Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation
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Author:
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Dorel, Ruth; de Mendoza, Paula; Calleja, Pilar; Pascual, Sergio; González-Cantalapiedra, Esther; Cabello, Noemí; Echavarren, Antonio M.
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Abstract:
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The synthesis of a new C3v‐symmetric crushed fullerene C60H24 (5) has been accomplished in three steps from truxene through sixfold palladium‐catalyzed intramolecular arylation of a syn‐trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the formation of C60, as detected by LDI‐MS. |
Publication date:
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2016-05-02 |
Subject(s):
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Quimica |
Rights:
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L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/ |
Pages:
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3171 p. |
Document type:
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Article Article - Draft |
DOI:
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10.1002/ejoc.201600311
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Published by:
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Eur. J. Org. Chem.
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