Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation

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dc.contributor.author	Dorel, Ruth
dc.contributor.author	de Mendoza, Paula
dc.contributor.author	Calleja, Pilar
dc.contributor.author	Pascual, Sergio
dc.contributor.author	González-Cantalapiedra, Esther
dc.contributor.author	Cabello, Noemí
dc.contributor.author	Echavarren, Antonio M.
dc.date.accessioned	2018-06-15T13:15:35Z
dc.date.available	2018-06-15T13:15:35Z
dc.date.issued	2016-05-02
dc.identifier.uri	http://hdl.handle.net/2072/326404
dc.format.extent	3171 p.
dc.language.iso	eng
dc.publisher	Eur. J. Org. Chem.
dc.rights	L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source	RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other	Quimica
dc.title	Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/draft
dc.embargo.terms	cap
dc.relation.projectID	info:eu-repo/grantAgreement/EC/FP7/321066
dc.identifier.doi	10.1002/ejoc.201600311
dc.rights.accessLevel	info:eu-repo/semantics/openAccess
dc.description.abstract	The synthesis of a new C3v‐symmetric crushed fullerene C60H24 (5) has been accomplished in three steps from truxene through sixfold palladium‐catalyzed intramolecular arylation of a syn‐trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the formation of C60, as detected by LDI‐MS.

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