Access to indolines from primary phenylethylamines by an unexpected palladium- catalyzed C-H functionalization process

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Title:	Access to indolines from primary phenylethylamines by an unexpected palladium- catalyzed C-H functionalization process
Author:	Mancinelli, Andrea; Albert Mach, Joan; Ariza Piquer, Xavier; Barrios Moreno, Leoní Alejandra; García Gómez, Jordi; Gómez, Roberto; Granell Sanvicente, Jaime Ramón
Other authors:	Universitat de Barcelona
Abstract:	A new method for the preparation of 2,2-disubstituted indolines from 2-phenylethylamines was developed under Pd catalysis and PhI(OAc)2 as oxidant. Imines derived from 2-pyridinecarboxaldehyde were formed in situ to direct a C-H activation process. The resulting imines were also oxidized to the corresponding amides in the same Pd-catalyzed process to obtain the final indoline as a picolinamide.
Subject(s):	-Pal·ladi (Element químic) -Catàlisi -Palladium -Catalysis
Rights:	cc-by (c) Mancinelli, Andrea et al., 2019 http://creativecommons.org/licenses/by/3.0/es
Document type:	Article Article - Published version
Published by:	Royal Society of Chemistry
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