Combining AlCl3·6H2O and an ionic liquid to prepare chlorohydrin esters from glycerol

dc.contributor.author
Villorbina Noguera, Gemma
dc.contributor.author
Tomàs, Albert
dc.contributor.author
Escribà i Gelonch, Marc
dc.contributor.author
Oromí Farrús, Mireia
dc.contributor.author
Eras i Joli, Jordi
dc.contributor.author
Balcells Fluvià, Mercè
dc.contributor.author
Canela i Garayoa, Ramon
dc.date.accessioned
2024-12-05T21:25:44Z
dc.date.available
2024-12-05T21:25:44Z
dc.date.issued
2016-11-03T12:52:35Z
dc.date.issued
2025-01-01
dc.date.issued
2009
dc.identifier
https://doi.org/10.1016/j.tetlet.2009.03.183
dc.identifier
0040-4039
dc.identifier
http://hdl.handle.net/10459.1/58371
dc.identifier.uri
http://hdl.handle.net/10459.1/58371
dc.description.abstract
We describe here the first example in which glycerol has been transformed into chlorohydrin esters using an ionic liquid and hydrated aluminium chloride. The method avoids using Crown-18 ether, which was needed to obtain a similar yield when KCl was used. Alkyl and aryl acids can be used, although yields are very dependent on the carboxylic acid used.
dc.description.abstract
This work was supported by a Grant-in-Aid from the Secretaría de Estado de Política Científica y Tecnológica of the Spanish Ministry of Education and Culture (contract Grant No.: CTQ2006-07451/PPQ).
dc.language
eng
dc.publisher
Elsevier
dc.relation
MIECI/PN2004-2007/CTQ2006-07451/PPQ
dc.relation
Reproducció del document publicat a https://doi.org/10.1016/j.tetlet.2009.03.183
dc.relation
Tetrahedron Letters, 2009, vol. 50, núm. 23, p. 2828–2830
dc.rights
(c) Elsevier, 2009
dc.rights
info:eu-repo/semantics/restrictedAccess
dc.subject
[BMIM][PF6]
dc.subject
Chlorohydrin esters
dc.subject
Glycerol
dc.subject
Hydrated aluminium chloride
dc.subject
Ionic liquid
dc.subject
Substitution
dc.title
Combining AlCl3·6H2O and an ionic liquid to prepare chlorohydrin esters from glycerol
dc.type
article
dc.type
publishedVersion


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