dc.contributor.author |
Wang, Xueqiang |
dc.contributor.author |
Nakajima, Masaki |
dc.contributor.author |
Serrano, Eloisa |
dc.contributor.author |
Martin, Ruben |
dc.date.accessioned |
2018-06-15T13:28:05Z |
dc.date.available |
2018-06-15T13:28:05Z |
dc.date.issued |
2016-11-17 |
dc.identifier.uri |
http://hdl.handle.net/2072/326406 |
dc.format.extent |
15531 p. |
dc.language.iso |
eng |
dc.publisher |
J. Am. Chem. Soc |
dc.rights |
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/ |
dc.source |
RECERCAT (Dipòsit de la Recerca de Catalunya) |
dc.subject.other |
Quimica |
dc.title |
Alkyl Bromides as Mild Hydride Sources in Ni-Catalyzed Hydroamidation of Alkynes with Isocyanates |
dc.type |
info:eu-repo/semantics/article |
dc.type |
info:eu-repo/semantics/draft |
dc.embargo.terms |
cap |
dc.relation.projectID |
info:eu-repo/grantAgreement/EC/FP7/277883 |
dc.identifier.doi |
10.1021/jacs.6b10351 |
dc.rights.accessLevel |
info:eu-repo/semantics/openAccess |
dc.description.abstract |
A catalytic hydroamidation of alkynes with isocyanates using alkyl bromides as hydride sources has been developed. The method turns parasitic β-hydride elimination into a strategic advantage, rapidly affording acrylamides with excellent chemo- and regioselectivity. |