dc.contributor.author
Fuertes Espinosa, Carles
dc.contributor.author
Gómez Torres, Alejandra
dc.contributor.author
Morales Martínez, Roser
dc.contributor.author
Rodríguez Fortea, Antonio
dc.contributor.author
Garcia Simon, Cristina
dc.contributor.author
Gándara, Felipe
dc.contributor.author
Imaz, Inhar
dc.contributor.author
Juanhuix, Judith
dc.contributor.author
Maspoch Comamala, Daniel
dc.contributor.author
Poblet Rius, Josep M.
dc.contributor.author
Echegoyen, Luis
dc.contributor.author
Ribas, Xavi
dc.identifier
https://ddd.uab.cat/record/206942
dc.identifier
urn:10.1002/anie.201806140
dc.identifier
urn:oai:ddd.uab.cat:206942
dc.identifier
urn:scopus_id:85051848496
dc.identifier
urn:articleid:15213773v57n35p11294
dc.identifier
urn:wos_id:000442340000030
dc.identifier
urn:altmetric_id:44050851
dc.identifier
urn:icn2uab:5610846
dc.identifier
urn:oai:egreta.uab.cat:publications/15d14588-3956-4274-baee-87a05b29a1fb
dc.description.abstract
Supramolecular nanocapsule 1⋅(BArF) is able to sequentially and selectively entrap recently discovered U@C and unprecedented ScCU@C, simply by soaking crystals of 1⋅(BArF) in a toluene solution of arc-produced soot. These species, selectively and stepwise absorbed by 1⋅(BArF), are easily released, obtaining highly pure fractions of U@C and ScCU@C in one step. ScCU@C represents the first example of a mixed metal actinide-based endohedral metallofullerene (EMF). Remarkably, the host-guest studies revealed that 1⋅(BArF) is able to discriminate EMFs with the same carbon cage but with different encapsulated cluster and computational studies provide support for these observations.
dc.format
application/pdf
dc.relation
Agència de Gestió d'Ajuts Universitaris i de Recerca 2017/SGR-264
dc.relation
Agència de Gestió d'Ajuts Universitaris i de Recerca 2017/SGR-629
dc.relation
Ministerio de Economía y Competitividad CTQ2016-77989-P
dc.relation
Agencia Estatal de Investigación CTQ2017-87269-P
dc.relation
Ministerio de Economía y Competitividad SEV-2013-0295
dc.relation
Angewandte Chemie (International ed. Internet) ; Vol. 57, Issue 35 (August 2018), p. 11294-11299
dc.rights
Aquest material està protegit per drets d'autor i/o drets afins. Podeu utilitzar aquest material en funció del que permet la legislació de drets d'autor i drets afins d'aplicació al vostre cas. Per a d'altres usos heu d'obtenir permís del(s) titular(s) de drets.
dc.rights
https://rightsstatements.org/vocab/InC/1.0/
dc.subject
Endohedral metallofullerenes
dc.subject
Supramolecular capsules
dc.title
Purification of Uranium-based Endohedral Metallofullerenes (EMFs) by Selective Supramolecular Encapsulation and Release
