Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI4AgI] Complexes: C􏰵��H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines

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Title:	Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI4AgI] Complexes: C��H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines
Author:	Smirnova, Ekaterina S.; Muñoz-Molina, José M.; Johnson, Alice; Bandeira, Nuno A. G.; Bo, Carles; Echavarren, Antonio M.
Abstract:	The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [AuI8] core, and pentanuclear [AuI4MI] (M=Cu, Ag) complexes is presented. The linear [AuI4] complex under- goes C��H functionalization of carbonyl compounds under mild reaction conditions. In addition, [AuI4AgI] catalyzes the carbonylation of primary amines to form ureas under homo- geneous conditions with efficiencies higher than those achieved by gold nanoparticles.
Publication date:	2016-05-11
Subject(s):	54
Rights:	L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
Pages:	7487 p.
Document type:	Article Article - Accepted version
DOI:	10.1002/anie.201603200
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