dc.contributor.author |
Smirnova, Ekaterina S. |
dc.contributor.author |
Muñoz-Molina, José M. |
dc.contributor.author |
Johnson, Alice |
dc.contributor.author |
Bandeira, Nuno A. G. |
dc.contributor.author |
Bo, Carles |
dc.contributor.author |
Echavarren, Antonio M. |
dc.date.accessioned |
2018-11-08T16:13:11Z |
dc.date.available |
2018-11-08T16:13:11Z |
dc.date.issued |
2016-05-11 |
dc.identifier.uri |
http://hdl.handle.net/2072/335520 |
dc.format.extent |
7487 p. |
dc.language.iso |
eng |
dc.rights |
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/ |
dc.source |
RECERCAT (Dipòsit de la Recerca de Catalunya) |
dc.subject.other |
54 |
dc.title |
Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI4AgI] Complexes: C�H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines |
dc.type |
info:eu-repo/semantics/article |
dc.type |
info:eu-repo/semantics/acceptedVersion |
dc.embargo.terms |
12 mesos |
dc.relation.projectID |
info:eu-repo/grantAgreement/EC/FP7/321066 |
dc.identifier.doi |
10.1002/anie.201603200 |
dc.rights.accessLevel |
info:eu-repo/semantics/openAccess |
dc.description.abstract |
The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [AuI8] core, and pentanuclear [AuI4MI] (M=Cu, Ag) complexes is presented. The linear [AuI4] complex under- goes CH functionalization of carbonyl compounds under mild reaction conditions. In addition, [AuI4AgI] catalyzes the carbonylation of primary amines to form ureas under homo- geneous conditions with efficiencies higher than those achieved by gold nanoparticles. |