Title:
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Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysis
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Author:
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Romero, Martín; Fra,Laura; Lishchynskyi, Anton; Martínez, Claudio; Streuff, Jan; Muñiz, Kilian
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Abstract:
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Acceptor-substituted N-H groups as found in carbamides and sulfonamides are readily activated through suitable unsaturated metal complexes applying the concept of metal-ligand bifunctionality. This process constitutes the basis for an enantioselective intramolecular addition of N-H groups onto activated alkenes. The resulting compounds can also be employed as catalyst precursors for transferhydrogenation. |
Publication date:
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2015 |
Subject(s):
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Amination Catalysis C-H functionalization Iodine Oxidation |
Rights:
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2016 Elsevier B.V. |
Document type:
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Article |
DOI:
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https://dx.doi.org/10.1016/j.tet.2015.03.028
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Published by:
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Elsevier
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Publish at:
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Tetrahedron
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Share:
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