Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation

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Title:	Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation
Author:	Mitra, Mainak; Lloret Fillol, Julio; Haukka, Matti; Costas Salgueiro, Miquel; Nordlander, Ebbe
Other authors:	Ministerio de Economía y Competitividad (Espanya); Ministerio de Ciencia e Innovación (Espanya); Generalitat de Catalunya. Agència de Gestió d'Ajuts Universitaris i de Recerca
Abstract:	A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors
Abstract:	This work has been supported by the European Union (the Erasmus Mundus program), the International Research Training Group Metal Sites in Biomolecules: Structures, Regulation and Mechanisms (www.biometals.eu), and COST Action CM1003. M.C. acknowledges ERC-29910, MINECO of Spain for CTQ2012- 37420-C02-01/BQU and CSD2010-00065, catalan DIUE (2009SGR637) and an ICREA academia award. J.Ll. thanks MICINN for a RyC contract
Subject(s):	-Oxidació -Oxidation -Ferro -- Compostos -Iron compounds -Catàlisi -Catalysis
Rights:	Attribution-NonCommercial 3.0 Spain http://creativecommons.org/licenses/by-nc/3.0/es/
Document type:	Article Article - Published version
Published by:	Royal Society of Chemistry (RSC)
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