Título:
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A robust and unique iron(II) mosaic-like MOF
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Autor/a:
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Fernandez-Bartolome, Estefania; Santos, Jose; Khodabakhshi, Saeed; McCormick, Laura J.; Teat, Simon J.; Saenz de Pipaon, Cristina; Galan-Mascaros, Jose Ramon; Martın, Nazario; Sanchez Costa, Jose
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Abstract:
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A novel extended triazole-based ligand (PM-Tria) has been synthe- sized and an unprecedented MOF 3D has serendipitously been formed by assembling iron(II), PM-Tria ligand and fluoride anions. This MOF contains a perfectly linear one-dimensional {Fe(II)–F}n bridging chain that shows an antiferromagnetic behaviour. Further- more, the structure is compared with a 14th century mosaic found in the Alhambra Palace in Granada showing a surprising symmetry resemblance. |
Fecha de creación:
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30-04-2018 |
Materia(s):
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54 |
Derechos:
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L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/ |
Páginas:
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5526 p. |
Tipo de documento:
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Artículo Artículo - Versión aceptada |
DOI:
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10.1039/c8cc01561a
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Compartir:
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