dc.contributor
Agencia Estatal de Investigación
dc.contributor.author
Pla i Quintana, Anna
dc.contributor.author
Roglans i Ribas, Anna
dc.date.accessioned
2024-06-18T13:57:24Z
dc.date.available
2024-06-18T13:57:24Z
dc.date.issued
2022-02-16
dc.identifier
http://hdl.handle.net/10256/21122
dc.identifier.uri
https://hdl.handle.net/10256/21122
dc.description.abstract
[2+2+2] Cycloaddition reaction is a captivating process that assembles six-membered rings from three unsaturations with complete atom economy. Of the multiple transition metals that can be used to catalyze this reaction, rhodium offers many advantages. These include high activity and versatility, but especially the ability to easily tune the reactivity and selectivity by the modification of the ligands around the metal. In this personal account, we summarize our endeavours in the development of efficient and sustainable [2+2+2] cycloaddition reactions to prepare products of interest, develop conditions in which the catalyst can be recovered and reused, and understand the mechanistic details that govern the selectivity of the processes
dc.description.abstract
This research was funded by the Ministerio de Ciencia e Innovación (projects CTQ2017-85341-P, PID2020-113711GB-I00 MCIN/AEI/10.13039/501100011033) and the Generalitat de Catalunya
(Project 2017-SGR-39)
dc.format
application/pdf
dc.publisher
MDPI (Multidisciplinary Digital Publishing Institute)
dc.relation
info:eu-repo/semantics/altIdentifier/doi/10.3390/molecules27041332
dc.relation
info:eu-repo/semantics/altIdentifier/eissn/1420-3049
dc.relation
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-85341-P/ES/AVANCES EN LA REACTIVIDAD DE FULLERENOS Y NANOTUBOS: ESTUDIOS TEORICO-EXPERIMENTALES DE CICLACIONES CATALIZADAS POR METALES DE TRANSICION/
dc.relation
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-113711GB-I00/ES/DISEÑO Y SINTESIS DE FULLERENOS PARA LA CONSTRUCCION DE CELDAS SOLARES HIBRIDAS DE PEROVSKITA Y FULERENOS D ALTO RENDIMIENTO. UN ENFOQUE EXPERIMENTAL Y COMPUTACIONAL SINERGICO/
dc.rights
Attribution 4.0 International (CC BY 4.0)
dc.rights
https://creativecommons.org/licenses/by/4.0/
dc.rights
info:eu-repo/semantics/openAccess
dc.source
Molecules, 2022, vol. 27, núm. 4, p. 1332
dc.source
Articles publicats (D-Q)
dc.source
Pla i Quintana, Anna Roglans i Ribas, Anna 2022 The Choice of Rhodium Catalysts in [2+2+2] Cycloaddition Reaction: A Personal Account Molecules 27 4 1332
dc.subject
Reaccions d'addició
dc.subject
Ciclització (Química)
dc.subject
Addition reactions
dc.subject
Ring formation (Chemistry)
dc.subject
Catalitzadors metàl·lics de transició
dc.subject
Transition metal catalysts
dc.title
The Choice of Rhodium Catalysts in [2+2+2] Cycloaddition Reaction: A Personal Account
dc.type
info:eu-repo/semantics/article
dc.type
info:eu-repo/semantics/publishedVersion
