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A Superior and accessible cavitand receptor for the binding of monoterpenes and sesquiterpenes in water

To access the full text documents, please follow this link: https://hdl.handle.net/10256/26598

Author

Marchi Luciano, Hugo

Lopez Coll, Ricard

Álvarez Yebra, Rubén

Lledó Ponsati, Agustí

Other authors

Agencia Estatal de Investigación

Publication date

2025-02-04



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Abstract

A water-soluble receptor based on resorcin[4]arene featuring 8 solubilising carboxylate units (BC4) has been obtained in a straightforward manner without chromatographic purifications. BC4 is soluble in water in a wide range of pH, and is able to accommodate guests of different sizes and shapes, including monoterpenes and sesquiterpenes, providing enhanced binding capabilities with respect to previously reported analogues. The molecular recognition events within BC4 are sensitive to subtle changes in guest shape and size, as illustrated by disparate exchange kinetics observed among the guests tested

We are grateful for financial support from grants PID2020-113181GB-I00, TED2021-130573B-I00, PID2023-146498NB-I00, and REQ2021_B_05 funded by MICIU/AEI/10.13039/501100011033 and by the European Union NextGenerationEU/PRTR. We thank AGAUR/Generalitat de Catalunya for funding (2021SGR623) and for a pre-doctoral fellowship to R. L. (2020 FI_B 00132)

Open Access funding provided thanks to the CRUE-CSIC agreement with the RSC

Document Type

Article

Published version

peer-reviewed

Language

English

Subjects and keywords

Química supramolecular; Terpens; Reconeixement molecular; Supramolecular chemistry; Terpenes; Molecular recognition

Publisher

Royal Society of Chemistry

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info:eu-repo/semantics/altIdentifier/doi/10.1039/D5QO00161G

info:eu-repo/semantics/altIdentifier/eissn/2052-4129

PID2020-113181GB-I00

TED2021-130573B-I00

PID2023-146498NB-I00

info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/TED2021-130573B-I00/ES/TECNOLOGÍAS DE QUÍMICA SUPRAMOLECULAR PARA MATERIALES FOTOVOLTAICOS DE NUEVA GENERACIÓN BASADOS EN CARBONO/

info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2023-146498NB-I00/ES/ESPACIOS CONFINADOS QUIRALES PARA APLICACIONES EN CATALISIS ASIMETRICA Y MATERIALES QUIROPTICOS/

info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-113181GB-I00/ES/ESPACIOS CONFINADOS FLEXIBLES PARA QUIMICA BIOINSPIRADA/

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Rights

Reconeixement-NoComercial 4.0 Internacional

http://creativecommons.org/licenses/by-nc/4.0

This item appears in the following Collection(s)

Articles publicats Departament de Química [1217]