Performance comparison of a group of thermal conductivity enhancement methodology in phase change material for thermal storage application

Abstract

Phase change materials (PCM) are able to store thermal energy when becoming liquids and to release it when freezing. Recently the use of PCM materials for thermal energy storage (TES) at high temperature for Concentrated Solar Power (CSP) technology has been widely studied. One of the main investigated problems is the improvement of their low thermal conductivity. This paper looks at the current state of research in the particular field of thermal conductivity enhancement (TCE) mechanisms of PCM to be used as TES. This work considers a numerical approach to evaluate the performance of a group of TCE solutions composed by particular configurations of two of the principal TCE systems found on the literature: finned pipes and conductive foams. The cases are compared against a single PCM case, used as reference. Three different grades of graphite foams have been studied, presenting a charge time 100 times lower than the reference case for the same capacity. For fins two materials are analyzed: carbon steel and aluminum. The charge times of fin cases are from 3 to 15 times faster, depending on the amount and type of material employed. The internal mechanisms are analyzed to understand the results and locate possible improvement.

The research leading to these results has received funding from CDTI Thesto (ITC-20111050) innterconecta Thesto). The work partially funded by the Spanish government (ENE2011-28269-C03-02 and ENE2015-64117-C5-1-R). The authors would like to thank the Catalan Government for the quality accreditation given to the research group GREA (2014 SGR 123). The research leading to these results has received funding from the European Union’s Seventh Framework Programme (FP7/ 2007e2013) under grant agreement n PIRSES-GA-2013-610692 (INNOSTORAGE) and from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 657466 (INPATH-TES).