Synthesis of (+)-Schisanwilsonene A by Tandem Gold-Catalyzed Cyclization/1,5-Migration/Cyclopropanation

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Title:	Synthesis of (+)-Schisanwilsonene A by Tandem Gold-Catalyzed Cyclization/1,5-Migration/Cyclopropanation
Author:	Gaydou, Morgane; R. E. Miller; Delpont, Nicolas; Ceccon, Julien; Echavarren, Antonio M.
Abstract:	The first total synthesis of the antiviral (+)-schisanwilsonene A has been completed using a fully stereoselective tandem cyclization/1,5-migration/intermolecular cyclopropanation. The key reaction sequence is catalyzed by gold.
Publication date:	2013
Subject(s):	enynes gold small ring systems terpenoids total synthesis
Rights:	© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Document type:	Article
DOI:	https://dx.doi.org/10.1002/anie.201302411
Published by:	Wiley
Publish at:	Angew. Chem. Int. Ed.
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