Synthesis of (+)-Schisanwilsonene A by Tandem Gold-Catalyzed Cyclization/1,5-Migration/Cyclopropanation

Gaydou, Morgane; R. E. Miller; Delpont, Nicolas; Ceccon, Julien; Echavarren, Antonio M.

Synthesis of (+)-Schisanwilsonene A by Tandem Gold-Catalyzed Cyclization/1,5-Migration/Cyclopropanation

Author

Gaydou, Morgane

R. E. Miller

Delpont, Nicolas

Ceccon, Julien

Echavarren, Antonio M.

Publication date

2013

Abstract

<p> The first total synthesis of the antiviral (+)-schisanwilsonene A has been completed using a fully stereoselective tandem cyclization/1,5-migration/intermolecular cyclopropanation. The key reaction sequence is catalyzed by gold.</p>

Document Type

Article

Language

English

Subject

enynes; gold; small ring systems; terpenoids; total synthesis

Publisher

Wiley

Version of

Angew. Chem. Int. Ed.

Grant Agreement Number

CTQ2010-16088/BQU

Agreement 321066

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MICINN

ERC

AGAUR

Proyectos I+D

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SGR

CATGOLD

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anie.201302411(rev).docx

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Synthesis of (+)-Schisanwilsonene A by Tandem Gold-Catalyzed Cyclization/1,5-Migration/Cyclopropanation

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