Clickable Complexing Agents: Functional Crown Ethers for Immobilisation Onto Polymers and Magnetic Nanoparticles

Abstract

<p style="text-align: justify;"> Crown ethers and monoazacrown ethers supported onto well defined cobalt and Fe₃O₄ magnetic nanoparticles have been prepared and used as magnetically recoverable extracting materials for Pb²⁺ from aqueous and organic solutions. The assembly of the functional nanoparticles involves the integration of the complexing units by means of a copper-catalysed alkyne&ndash;azide cycloaddition reaction leading to a 1,2,3-triazole linker. The same binding motifs have been also used to functionalise polystyrene (PS) and polystyrene-polyethyleneglycol (PS-PEG) resins, and the resulting materials were also employed in the removal of Pb²⁺ from solutions. The relative merits of these two approaches are compared.</p>