Ni-catalyzed Regioselective Hydrocarboxylation of Alkynes with CO2 by Using Simple Alcohols as Proton Sources

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Title:	Ni-catalyzed Regioselective Hydrocarboxylation of Alkynes with CO2 by Using Simple Alcohols as Proton Sources
Author:	Wang, Xueqiang; Nakajima, Masaki; Ruben Martin
Abstract:	A mild and user-friendly Ni-catalyzed regioselective hydrocarboxylation of alkynes with CO2 (1 bar) is described. This protocol is characterized by a wide scope while obviating the need for sensitive organometallic species and by an unprecedented regioselectivity pattern using simple alcohols as proton sources.
Publication date:	2015
Rights:	© 2015 American Chemical Society
Document type:	Article
DOI:	https://dx.doi.org/10.1021/jacs.5b05513
Published by:	Journal of the American Chemical Society,
Publish at:	J. Am. Chem. Soc
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