Defined Palladium Phthalimidato Catalysts for Improved Oxidative Amination

Abstract

<p> <style type="text/css"> <!-- /* Font Definitions */ @font-face {font-family:Arial; panose-1:2 11 6 4 2 2 2 2 2 4; mso-font-charset:0; mso-generic-font-family:auto; mso-font-pitch:variable; mso-font-signature:-536859905 -1073711037 9 0 511 0;} @font-face {font-family:Arial; panose-1:2 11 6 4 2 2 2 2 2 4; mso-font-charset:0; mso-generic-font-family:auto; mso-font-pitch:variable; mso-font-signature:-536859905 -1073711037 9 0 511 0;} @font-face {font-family:"MS Mincho"; mso-font-alt:"ＭＳ 明朝"; mso-font-charset:0; mso-generic-font-family:auto; mso-font-pitch:variable; mso-font-signature:0 0 0 0 0 0;} /* Style Definitions */ p.MsoNormal, li.MsoNormal, div.MsoNormal {mso-style-unhide:no; mso-style-qformat:yes; mso-style-parent:""; margin:0cm; margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:12.0pt; font-family:"Times New Roman"; mso-fareast-font-family:"MS Mincho"; mso-ansi-language:DE; mso-fareast-language:JA;} p.Abstract, li.Abstract, div.Abstract {mso-style-name:Abstract; mso-style-unhide:no; mso-style-qformat:yes; margin-top:0cm; margin-right:0cm; margin-bottom:18.0pt; margin-left:0cm; text-align:justify; line-height:11.25pt; mso-line-height-rule:exactly; mso-pagination:widow-orphan; font-size:8.0pt; mso-bidi-font-size:10.0pt; font-family:Arial; mso-fareast-font-family:"MS Mincho"; mso-bidi-font-family:"Times New Roman"; mso-ansi-language:EN-GB; mso-fareast-language:JA;} .MsoChpDefault {mso-style-type:export-only; mso-default-props:yes; font-size:10.0pt; mso-ansi-font-size:10.0pt; mso-bidi-font-size:10.0pt; mso-fareast-font-family:"MS Mincho";} @page WordSection1 {size:612.0pt 792.0pt; margin:72.0pt 90.0pt 72.0pt 90.0pt; mso-header-margin:36.0pt; mso-footer-margin:36.0pt; mso-paper-source:0;} div.WordSection1 {page:WordSection1;} --> </style> </p> <p class="Abstract"> <span lang="EN-GB">New bisphthalimidato palladium(II) complexes have been synthesized, isolated and structurally characterized. As demonstrated for over 30 examples, they constitute superior catalysts for oxidative amination reactions of alkenes with phthalimide as nitrogen source. This work streamlines vicinal difunctionalization of alkenes and provides access to significantly improved and experimentally simplified synthetic protocols.</span></p>