dc.contributor.author
Martínez, Claudio
dc.contributor.author
Pérez, Edwin G.
dc.contributor.author
Iglesias, Álvaro
dc.contributor.author
Escudero-Adán, Eduardo C.
dc.contributor.author
Muñiz, Kilian
dc.date.accessioned
2018-01-15T16:03:52Z
dc.date.accessioned
2018-02-15T10:28:51Z
dc.date.accessioned
2024-04-23T10:34:22Z
dc.date.available
2018-01-15T16:03:52Z
dc.date.available
2018-02-15T10:28:51Z
dc.date.available
2024-04-23T10:34:22Z
dc.identifier.uri
http://hdl.handle.net/2072/305904
dc.description.abstract
<p> Palladium catalysis enables the regioselective difunctionalization of alkenes using saccharin as the nitrogen source in the initial step of aminopalladation. Depending on the reaction conditions, diamination or aminooxygenation pathways can be accessed using hypervalent iodine reagents as the terminal oxidants. The aminooxygenation of allylic ethers originates from an unprecedented ambident behavior of saccharin. The participating palladium catalysts contain a palladium–saccharide unit. Two representative complexes of this type could be isolated and characterized.</p>
dc.publisher
ACS Publications
dc.relation
Ministerio de Economia y Competitivad
dc.relation
CTQ2011-25027 to K. M., and Severo Ochoa Excellence Accreditation 2014-2018 to ICIQ,
dc.rights
2016 American Chemical Society
dc.title
Regioselective Intermolecular Diamination and Aminooxygenation of Alkenes with Saccharin
dc.type
info:eu-repo/semantics/article
dc.relation.projectID
CTQ2011-25027
dc.relation.projectID
SEV-2013-0319
dc.identifier.doi
https://doi.org/10.1021/acs.orglett.6b01368
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
