dc.contributor.author |
Gutov, Oleksii V. |
dc.contributor.author |
Molina, Sonia |
dc.contributor.author |
Escudero-Adan, Eduardo C. |
dc.contributor.author |
Shafir, Alexandr |
dc.date.accessioned |
2018-01-15T16:03:59Z |
dc.date.accessioned |
2018-02-15T10:28:59Z |
dc.date.available |
2018-01-15T16:03:59Z |
dc.date.available |
2018-02-15T10:28:59Z |
dc.date.issued |
2016 |
dc.identifier.uri |
http://hdl.handle.net/2072/226286 |
dc.identifier.uri |
http://hdl.handle.net/2072/305928 |
dc.language.iso |
eng |
dc.publisher |
Wiley |
dc.relation |
MINECO |
dc.relation |
AGAUR |
dc.relation |
cellex Foundation |
dc.relation |
European Commission |
dc.relation |
I+D+I, Severo Ochoa Excellence Accreditation, Marie Curie |
dc.relation.ispartof |
Chemistry A European Journal |
dc.subject.other |
amino acids |
dc.subject.other |
metal–organic frameworks |
dc.subject.other |
modulated synthesis |
dc.subject.other |
proline |
dc.subject.other |
zirconium |
dc.title |
Modulation by Amino Acids: Toward Superior Control in the Synthesis of Zirconium Metal–Organic Frameworks |
dc.type |
info:eu-repo/semantics/article |
dc.relation.projectID |
CTQ2013-46705-R |
dc.relation.projectID |
SEV-2013-0319 |
dc.relation.projectID |
2014SGR1192 |
dc.relation.projectID |
info:eu-repo/grantAgreement/EC/FP7/62372 |
dc.identifier.doi |
https://dx.doi.org/10.1002/chem.201600898 |
dc.rights.accessLevel |
info:eu-repo/semantics/openAccess |
dc.description.abstract |
The synthesis of zirconium metal–organic frameworks (Zr MOFs) modulated by various amino acids, including l-proline, glycine, and l-phenylalanine, is shown to be a straightforward approach toward functional-group incorporation and particle-size control. High yields in Zr-MOF synthesis are achieved by employing 5 equivalents of the modulator at 120 °C. At lower temperatures, the method provides a series of Zr MOFs with increased particle size, including many suitable for single-crystal X-ray diffraction studies. Furthermore, amino acid modulators can be incorporated at defect sites in Zr MOFs with an amino acid/ligand ratio of up to 1:1, depending on the ligand structure and reaction conditions. The MOFs obtained through amino acid modulation exhibit an improved CO2-capture capacity relative to nonfunctionalized materials. |