dc.contributor.author
Martín, Carmen
dc.contributor.author
Whiteoak, Cristopher J.
dc.contributor.author
Martin, Eddy
dc.contributor.author
Escudero-Adán, Eduardo C.
dc.contributor.author
Galán-Mascarós, José-Ramón
dc.contributor.author
Klei, Arjan W.
dc.date.accessioned
2018-01-15T16:04:02Z
dc.date.accessioned
2018-02-15T10:29:01Z
dc.date.accessioned
2024-04-23T10:36:05Z
dc.date.available
2018-01-15T16:04:02Z
dc.date.available
2018-02-15T10:29:01Z
dc.date.available
2024-04-23T10:36:05Z
dc.identifier.uri
http://hdl.handle.net/2072/305935
dc.description.abstract
<p> Co(II) complexes of aminotrisphenolate<br /> ((ArO)3N3−) ligands can be prepared straightforwardly in high<br /> yield. X-ray analysis reveals these complexes to comprise of two<br /> different hemispheres, one containing an anionic Co((ArO)3N)−<br /> and the other a cationic (ArO)3NH+ unit, which are associated<br /> through hydrogen bonding. These Co(II) complexes can be<br /> easily converted into their Co(III) analogues in air in the<br /> presence of suitable bases such as dimethylaminopyridine and<br /> 2,2′-bipyridine, and the structural features and magnetic properties<br /> of these latter compounds are also reported.</p>
dc.relation
ERC Stg Grant CHEMCOMP
dc.relation
Marie Curie,Cofund
dc.relation
Icrea,MINECO,Severo Ochoa,ERC Stg Grant CHEMCOMP,Marie Curie,Cofund
dc.relation.ispartof
Inorg. Chem
dc.rights
© 2014 American Chemical Society
dc.title
Synthesis and Structural Features of Co(II) and Co(III) Complexes Supported by Aminotrisphenolate Ligand Scaffolds
dc.type
info:eu-repo/semantics/article
dc.relation.projectID
CTQ-2011- 27385
dc.relation.projectID
Severo Ochoa Excellence Accreditation 2014-2018 (SEV-2013-0319)
dc.identifier.doi
https://doi.org/10.1021/ic501883z
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
