dc.contributor.author
Lidia Clot-Almenara
dc.contributor.author
Carles Rodríguez-Escrich
dc.contributor.author
Laura Osorio-Planes
dc.contributor.author
Miquel A. Pericàs
dc.date.accessioned
2018-01-15T16:04:05Z
dc.date.accessioned
2018-02-15T10:29:03Z
dc.date.accessioned
2024-04-23T10:36:18Z
dc.date.available
2018-01-15T16:04:05Z
dc.date.available
2018-02-15T10:29:03Z
dc.date.available
2024-04-23T10:36:18Z
dc.identifier.uri
http://hdl.handle.net/2072/305939
dc.description.abstract
<p> The widely applicable TRIP phosphoric acid catalyst has been immobilized on polystyrene using a copolymerization-based strategy. The resin (<strong>PS-TRIP</strong>) has proven to be highly active and enantioselective in the asymmetric allylboration of aldehydes. Moreover, it has shown to be extremely robust, as it can be reused for 18 times, after which it still retained its activity. Lastly, to further prove the benefits of the immobilization, a continuous flow experiment spanning 28 h has been carried out with very high yields and ee’s.</p> <p> </p>
dc.publisher
ACS Publications
dc.relation
DEC Generalitat de Catalunya founds
dc.relation
Proyectos I+D+I – Retos 2015, Severo Ochoa Excellence
dc.relation.ispartof
ACS Catalysis
dc.rights
Copyright © 2017 American Chemical Society
dc.subject.other
chiral phosphoric acids
dc.subject.other
enantioselective catalysis
dc.subject.other
flow chemistry
dc.subject.other
organocatalysis
dc.subject.other
polystyrene-supported catalysts
dc.title
Polystyrene-Supported TRIP: A Highly Recyclable Catalyst for Batch and Flow Enantioselective Allylation of Aldehydes
dc.type
info:eu-repo/semantics/lecture
dc.relation.projectID
CTQ2015- 69136-R
dc.relation.projectID
SEV-2013-0319
dc.relation.projectID
2014SGR827
dc.identifier.doi
https://doi.org/10.1021/acscatal.6b02621
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
