Enantioselective Total Synthesis of (−)-Nardoaristolone B via a Gold(I)-Catalyzed Oxidative Cyclization

dc.contributor.author
Homs, Anna
dc.contributor.author
Muratore, Michael E
dc.contributor.author
Echavarren, Antonio M
dc.date.accessioned
2018-03-26T14:28:54Z
dc.date.accessioned
2024-04-23T10:17:07Z
dc.date.available
2018-03-26T14:28:54Z
dc.date.available
2024-04-23T10:17:07Z
dc.date.created
2014-12-07
dc.date.issued
2015-01-07
dc.identifier.uri
http://hdl.handle.net/2072/307093
dc.description.abstract
The first enantioselective total synthesis of (−)-nardoaristolone B is accomplished by the implementation of an enantio- and diastereoselective copper(I)-catalyzed conjugate addition/enolate trapping sequence and a gold(I)-catalyzed oxidative cyclization (intermolecular oxidant), employed for the first time in total synthesis.
eng
dc.format.extent
3 p.
cat
dc.language.iso
eng
cat
dc.publisher
American Chemical Society
cat
dc.relation.ispartof
Organic Letters
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dc.rights
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
54 - Química
cat
dc.title
Enantioselective Total Synthesis of (−)-Nardoaristolone B via a Gold(I)-Catalyzed Oxidative Cyclization
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/publishedVersion
cat
dc.subject.udc
54
cat
dc.subject.udc
547
cat
dc.embargo.terms
cap
cat
dc.identifier.doi
https://doi.org/10.1021/ol503531n
dc.rights.accessLevel
info:eu-repo/semantics/openAccess


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