dc.contributor.author
Wang, Yahui
dc.contributor.author
Muratore, Michael E
dc.contributor.author
Echavarren, Antonio M
dc.date.accessioned
2018-03-26T14:37:58Z
dc.date.accessioned
2024-04-23T10:17:14Z
dc.date.available
2018-03-26T14:37:58Z
dc.date.available
2024-04-23T10:17:14Z
dc.date.created
2015-03-18
dc.date.issued
2015-03-18
dc.identifier.uri
http://hdl.handle.net/2072/307096
dc.description.abstract
By reviewing the recent progress on the eluci- dation of the structure of gold carbenes and the defini- tions of metal carbenes and carbenoids, we recommend to use the term gold carbene to describe gold carbene-like intermediates, regardless of whether the carbene or car- bocation extreme resonance dominates. Gold carbenes, because of the weak metal-to-carbene p-back-donation and their strongly electrophilic reactivity, could be classi- fied into the broader family of Fischer carbenes, although their behavior and properties are very specific.
eng
dc.format.extent
8 p.
cat
dc.publisher
Wiley VCH
cat
dc.relation.ispartof
Chemistry – A European Journal
cat
dc.rights
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc/4.0/
dc.source
RECERCAT (Dipòsit de la Recerca de Catalunya)
dc.subject.other
54 - Química
cat
dc.title
Gold Carbene or Carbenoid: Is There a Difference?
cat
dc.type
info:eu-repo/semantics/article
cat
dc.type
info:eu-repo/semantics/publishedVersion
cat
dc.identifier.doi
https://doi.org/10.1002/chem.201406318
dc.rights.accessLevel
info:eu-repo/semantics/openAccess
