dc.contributor.author |
Wang, Yahui |
dc.contributor.author |
Muratore, Michael E |
dc.contributor.author |
Echavarren, Antonio M |
dc.date.accessioned |
2018-03-26T14:37:58Z |
dc.date.available |
2018-03-26T14:37:58Z |
dc.date.created |
2015-03-18 |
dc.date.issued |
2015-03-18 |
dc.identifier.uri |
http://hdl.handle.net/2072/307096 |
dc.format.extent |
8 p. |
dc.language.iso |
eng |
dc.publisher |
Wiley VCH |
dc.relation.ispartof |
Chemistry – A European Journal |
dc.rights |
L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons: http://creativecommons.org/licenses/by-nc/4.0/ |
dc.source |
RECERCAT (Dipòsit de la Recerca de Catalunya) |
dc.subject.other |
54 - Química |
dc.title |
Gold Carbene or Carbenoid: Is There a Difference? |
dc.type |
info:eu-repo/semantics/article |
dc.type |
info:eu-repo/semantics/publishedVersion |
dc.subject.udc |
54 - Química |
dc.subject.udc |
547 - Química orgánica |
dc.embargo.terms |
cap |
dc.rights.accessLevel |
info:eu-repo/semantics/openAccess |
dc.description.abstract |
By reviewing the recent progress on the eluci- dation of the structure of gold carbenes and the defini- tions of metal carbenes and carbenoids, we recommend to use the term gold carbene to describe gold carbene-like intermediates, regardless of whether the carbene or car- bocation extreme resonance dominates. Gold carbenes, because of the weak metal-to-carbene p-back-donation and their strongly electrophilic reactivity, could be classi- fied into the broader family of Fischer carbenes, although their behavior and properties are very specific. |